Structural investigation of the synthetic CaAn(PO4)2 (An = Th and Np) cheralite-like phosphates     

Philippe E. Raison  Regis Jardin  Daniel Bouëxière  Rudy J. M. Konings  Thorsten Geisler  Claudiu C. Pavel  Jean Rebizant  Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609

The crystallographic structures of the synthetic cheralite, CaTh(PO₄)₂, and its homolog CaNp(PO₄)₂ have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO₄ (Ln = La to Gd). The space group is P2₁/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO₄)₂ are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R _wp = 4.87%, R _p = 3.69% and R _B = 3.99%. For CaNp(PO₄)₂, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R _wp = 6.74%, R _p = 5.23%, and R _B = 6.05%. The results indicate significant distortions of bond length and angles of the PO₄ tetrahedra in CaTh(PO₄)₂ and to a lesser extent in CaNp(PO₄)₂. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO₄)₂. A comparison with the isostructural compounds LnPO₄ (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca²⁺ and Th⁴⁺ introduces a distortion of the PO₄ tetrahedra.  相似文献   

Seasonal DOC accumulation in the Black Sea: a regional explanation for a general mechanism   总被引：2，自引：0，他引：2  

Gustave Cauwet  Gaëlle Dliat  Anton Krastev  Galina Shtereva  Sylvie Becquevort  Christiane Lancelot  Andr Momzikoff  Alain Saliot  Adriana Cociasu  Lucia Popa 《Marine Chemistry》2002,79(3-4)

During three cruises in the Black Sea, organised in July 1995 and April–May 1997, biological and chemical parameters that can influence the carbon budget were measured in the water column on the NW shelf, particularly in the mixing zone with Danube River waters. We observed in early spring (end of April–May) conditions an important input of freshwater organisms that enhanced the microbial activity in the low salinity range. High bacterial activity regenerates nitrogen in the form of nitrates, but is also responsible for an important consumption of ammonium and phosphate, leading to a high N/P ratio and a strong deficit in phosphorus. The consequence is a limitation of phytoplankton development but also a production of carbohydrates that accumulate all along the salinity gradient. These mechanisms are responsible for a seasonal accumulation of dissolved organic carbon (DOC) that increases from 210 μM in winter to about 280 μM in summer. All this excess DOC disappears during winter, probably degraded by bacterial activity. The degradation of carbon-rich organic matter increases the phosphorus demand by bacteria bringing limitation to phytoplankton primary production.  相似文献   

Redefining active volcanoes: a discussion   总被引：2，自引：0，他引：2  

Alexandru Szakács 《Bulletin of Volcanology》1994,56(5):321-325

The analysis of the current definitions of active volcanoes indicates that they are empirical, conventional, inaccurate, nongeological, and arbitrarily constraining. Redefinition is therefore needed. One possible approach is to refine the current empirical definitions. A statistically reasonable and practical redefinition using a geologically based time convention-Holocene or 10000 years-is suggested. A set of time conditions according to volcano typology-i.e. 1000; 10000 and 100000 years for high-frequency basaltic shields, andesitic-dacitic composite volcanoes and low-frequency large silicic calderas, respectively-as further refinement of the empirical definition is also envisaged. Devising a phenomenological definition as a theoretical approach is another possibility, but in practice extant diagnostic means are still unsatisfactory to discriminate accurately between dormant and extinct volcanoes. As a consequence of the redefinition, a classification of volcanoes according to their eruptive status is proposed. Redefinition of active volcanoes might increase accuracy in the usage of basic terms in volcanology and influence volcanic hazard assessment and risk mitigation projects.  相似文献   

CMSAF products Cloud Fraction Coverage and Cloud Type used for solar global irradiance estimation     

Viorel Badescu  Alexandru Dumitrescu 《Meteorology and Atmospheric Physics》2016,128(4):525-535

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Comments on the article "Erosion calderas: origins, processes, structural and climatic control" by Karátson D., Thouret J.-C., Moriya I., Lomoschitz A. (1999) Bull Volcanol 61:174-193     

Alexandru Szakács  Michael Ort 《Bulletin of Volcanology》2001,63(4):289-290

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Search for Magnetic Monopoles and for Nuclearites with the MACRO Detector     

V. Popa 《Astrophysics and Space Science》2000,273(1-4):305-312

We discuss the searches for massive magnetic monopoles and for nuclearitesin the penetrating cosmic radiation performed with the MACRO detector. Independent monopole analysis were carried out using the scintillator, streamer tubes and nuclear track sub-detectors in different ranges of velocity. No candidates were found in several years of data taking; present upper flux limits are well below the Parker bound in a wide velocity range. For nuclearites only the scintillator and nuclear track sub-detectors were used.  相似文献   

Interplay of tectonics and neogene post-collisional magmatism in the intracarpathian region   总被引：6，自引：0，他引：6  

Ioan Seghedi  Ion Balintoni  Alexandru Szakcs 《Lithos》1998,45(1-4):483-497

Distribution of the Neogene calc-alkaline magmatism of the Carpathian arc is directly related in space and time to the kinematics of the two major terranes of the Intracarpathian area (Alcapa, Tisia-Getia) along the south-eastern border of the European plate. In the West Carpathians and adjacent areas, the volcanic activity occurred between 20–11 Ma, with large volumes of both acidic and intermediate rocks, generally distributed randomly, sometimes transversally to the orogenic belt and as rare small occurrences along the Flysch belt. In the East Carpathians, the volcanic rocks are distributed along the northern margin of the Zemplin block, the north–easternmost part of the Alcapa and eastward along the front of the Getic block, at the contact with European plate. Between Tokaj-Slanské-Vihorlat up to northern Cãlimani Mountains, the magmatism occurred between 14–9 Ma, and along the Cãlimani-Harghita chain between 9–0.2 Ma. The calc-alkaline magmatic rocks of the Apuseni Mountains are located in the interior of the Tisia block and occurred between 14–9 Ma. The generation of the calc-alkaline magmatism is considered here as the result of complex interplay between plate roll-back and lithospheric detachment tectonic processes and the break-off of the subducted plate, mostly in a post-collisional setting. (1) The magmatites of the Western Carpathians and the Pannonian basin were generated in direct relation to subduction roll-back processes, over the downgoing slab, during the period of lateral extrusion and back-arc extension. In this area, characterized by maximum crustal shortening, we can infer further delamination processes to explain the generation of magmas. (2) The magmatic rocks from the northern sector of the East Carpathians (Tokaj-Slanské-Vihorlat up to the Northern Cãlimani Mountains), resulted after subduction roll-back processes and an almost simultaneous break-off of the descending plate all along the arc segment during main clockwise rotation of the Intracarpathian terranes. (3) In the eastern sector of the East Carpathians (Cãlimani up to Harghita Mountains), the magmatic rocks were generated through partial melting of the subducted slab followed by gradual break-off of the subducted plate along strike (north to south). (4) The Apuseni Mts. magmatic activity resulted in transtensional tectonic regime by decompressional melting of lithospheric mantle, during the translation and rotation of Tisia-Getia block.  相似文献   

Deep seismic soundings in Romania     

Ion Cornea  Florin Rădulescu  Alexandru Pompilian  Adrian Sova 《Pure and Applied Geophysics》1981,119(6):1144-1156

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Changes in annual temperature extremes in the Carpathians since AD 1961   总被引：1，自引：1，他引：0  

Marius-Victor Birsan  Alexandru Dumitrescu  Dana Magdalena Micu  Sorin Cheval 《Natural Hazards》2014,74(3):1899-1910

The Carpathian Mountains region cover areas from seven countries of central and southeastern Europe, the mountain chain having major regional influences on the temperate climate, specific to latitudes between 43°N and 49°N. In order to identify changes in the annual temperature extremes, the Mann–Kendall nonparametric trend test has been applied to several thermal indices, recommended by the expert team on climate change detection and indices. The indices were computed from gridded daily datasets of minimum and maximum temperature at 0.1° resolution (~10 km), available online within the framework of the project CarpatClim (climate of the Carpathian region) for the period 1961–2010. The results show decreasing trends in cold-related indices, especially in the number of frost days, and increasing trends in warm-related ones. The trend patterns are consistent over the region, i.e., there are no mixed trends for a given index. Regional differences in climate extreme trends within the Carpathian region are related to altitude, rather than latitude. The number of summer days is increasing over the entire area, while the number of tropical nights presents upward trends mainly at lower elevations. The Warm Spell Duration Index presents upward trends over 60 % of the region. The (annual) East Atlantic pattern shows strong correlations with the warm-related indices. Our results are in agreement with previous temperature-related studies in the region.  相似文献   

Present climate and climate change over North America as simulated by the fifth-generation Canadian regional climate model     

Leo Šeparović  Adelina Alexandru  René Laprise  Andrey Martynov  Laxmi Sushama  Katja Winger  Kossivi Tete  Michel Valin 《Climate Dynamics》2013,41(11-12):3167-3201

The fifth-generation Canadian Regional Climate Model (CRCM5) was used to dynamically downscale two Coupled Global Climate Model (CGCM) simulations of the transient climate change for the period 1950–2100, over North America, following the CORDEX protocol. The CRCM5 was driven by data from the CanESM2 and MPI-ESM-LR CGCM simulations, based on the historical (1850–2005) and future (2006–2100) RCP4.5 radiative forcing scenario. The results show that the CRCM5 simulations reproduce relatively well the current-climate North American regional climatic features, such as the temperature and precipitation multiannual means, annual cycles and temporal variability at daily scale. A cold bias was noted during the winter season over western and southern portions of the continent. CRCM5-simulated precipitation accumulations at daily temporal scale are much more realistic when compared with its driving CGCM simulations, especially in summer when small-scale driven convective precipitation has a large contribution over land. The CRCM5 climate projections imply a general warming over the continent in the 21st century, especially over the northern regions in winter. The winter warming is mostly contributed by the lower percentiles of daily temperatures, implying a reduction in the frequency and intensity of cold waves. A precipitation decrease is projected over Central America and an increase over the rest of the continent. For the average precipitation change in summer however there is little consensus between the simulations. Some of these differences can be attributed to the uncertainties in CGCM-projected changes in the position and strength of the Pacific Ocean subtropical high pressure.  相似文献